Combined effects of structure and temperature on kinetics and free activatioin energy of reactions between trans-2,3-bis(3-bromo-5-nitrophenyl)oxirane and arenesulfonic acids.

Анотація

The combined effects of structure and temperature on the rate and free activation energy of reactions between trans-2,3-bis(3-bromo-5-nitrophenyl)oxirane and Y-substituted arenesulfonic acids (Y = 4-OCH3, 4-CH3, H, 4-Cl) in a mixture of dioxane with 1,2- dichloroethane (7:3, v/v) at 265, 281, and 298 K have been studied.